Volume 336
Main Index

Issues 1-2, Pages 1-285 (8 December 1987)

Principles and Applications of Organotransition Metal Chemistry : by J.P. Collman, L.S. Hegedus, J.R. Norton, and R.G. Finke, University Science Books, Mill Valley (California), 1987, ISBN 0-935702-51-2, x + 989 pages. ??12.75 Pages C22-C23 Michael F. Lappert

Coordination chemistry of siloles: reaction of η4-complexed endo-1-chloro-2,5-diphenylsilacyclopentadiene with lithium reagents. Synthesis of new carbenes, and the crystal structure of dicarbonylphenyl(η4-exo-1-methyl-1-oxy-2,5-diphenylsilacyclopentadiene) carbene iron Pages C1-C4 Francis H. Carré, Robert J. P. Corriu, Christian Guerin, Bernard J. L. Henner, Wong Wee Choy Wong Chi Man

Sixth International Conference on the Organometallic and Coordination Chemistry of Geramanuim, Tin and lead Page C23

A direct and specific sonochemically assisted preparation of Fe(C5Me5)(dppe)X (X = Cl, H) Pages C13-C16 Christophe Roger, Patrick Marseille, Christophe Salus, Jean-René Hamon, Claude Lapinte

On the relationship between M---M bond length and the presence of bridging CO ligands in M4(CO)12 complexes (M = Co, Rh, Ir) Pages C9-C12 Dario Braga, Fabrizia Grepioni

Unprecedented formation of a dihydropyridine dimer from carbon monoxide and pyridine mediated by a dioxodimesitylmolybdenum(VI) complex Pages C5-C8 Richard Laï, Sylvie Le Bot, Robert Faure

author index Page C24

The synthesis and electrochemistry of a novel ferrocene bis-porphyrin molecule Pages C17-C21 Paul D. Beer, Stefan S. Kurek

Etude de la métallation des carbamates d'hydroxy-5, -6, -7 et -8 quinoéine Pages 1-12 Alain Godard, Yves Robin, Guy Queguiner

Infrared spectra of cyclopentadienyl-alkali metal (Li, Na) ion pairs in tetrahydrofuran and hexamethylphosphoric triamide Pages 13-22 O. G. Garkusha, I. A. Garbuzova, B. V. Lokshin, A. N. Nesmeyanov, G. K. Borisov

Asymmetric aldol reactions using (4R-trans)-2-(1-methyl- ethenyl)-1,3,2-dioxaborolane-4,5-dicarboxylic acid, bis-ethyl ester, a chiral precursor of the acetone enolate Pages 23-28 Gian Paolo Boldrini, Luisa Lodi, Emilio Tagliavini, Claudio Trombini, Achille Umani-Ronchi

Borole derivatives : X. Syntheses of (η5-borole)metal complexes via borole ammonia adducts. Complexes of the chromium group metals and the crystal and molecular structures of tetracarbonyl [η5-(1-phenylborole)] chromium and its molybdenum analogue Pages 29-43 G. E. Herberich, B. Hessner, M. Negele, J. A. K. Howard

Configurations of silicon-centred radicals: the bis(trimethylsilyl)silyl radical Pages 45-48 Richard A. Jackson, Christopher J. Rhodes

Intramolecular interactions in compounds bearing Si---O---C---C---N or C---O---C---C---N fragments Pages 49-57 E. I. Brodskaya, M. G. Voronkov, D. D. Toryashinova, V. P. Baryshok, G. V. Ratovski, D. D. Chuvashev and, V. G. Efremov

Reaktionen Methyl- und Trimethylsubstituierter Vinylsilane- bzw. -Disilane mit LiBut Pages 59-81 N. Auner

Silaheterocyclen : II. Erzeugung und Cycloadditionsreaktionen der Neopentylsilaethene i=CHCH2But (R = H, Me) Pages 83-103 N. Auner

The mechanism of methyl loss from ionized methoxypentamethyldisilane: anchimeric assistance versus direct bond cleavage. Pages 105-113 Thomas Weiske, Semiha Akkök, Helmut Schwarz

Reactions of tin(IV) halides with [Fe2(η-C5H5)2(CO)4-n(CNMe)n] (n = 1 or 2) Pages 115-128 Pacelli Donegan, A. R. Manning

Action of HCl upon the Pt---C bonds in [NBu4]2[Pt(C6Cl5)4] and [NBu4]2[trans-PtCl2(C6Cl5)2]: synthesis of tris(pentachlorophenyl), [NBu4] [Pt(C6Cl5)3L] and dichloro-monopentachlorophenyl-platinate(II), [NBu4] [PtCl2(C6Cl5)L], complexes Pages 129-135 Rafael Usón, Juan Forniés, Milagros Tomás, Irene Ara, Babil Menjón

ESR of organometallics : V. Experimental and SCCC-MO studies on the anions of N-methyl-3-aroylpyrroles and their Cr(CO)3 complexes Pages 137-142 Niall J. Gogan, I. Sheila Jayasinghe, Pardeep K. Sayal

Formation de liaison C---C par couplage réducteur d'ions carbéniums arène chrome tricarbonyle Pages 143-151 Siden Top, Gérard Jaouen

Ferrocenylchalkogenide Pages 153-161 Max Herberhold, Peter Leitner

Reactions of lithium bis(μ-phenylphosphido)-bis(tricarbonyliron), (μ-PhPLi)2Fe2(CO)6, with organic halides. A novel anionic rearrangement of a chelating diphosphido ligand Pages 163-182 Dietmar Seyferth, Timothy G. Wood, Richard S. Henderson

Synthesis of heterobimetallic complexes of N-ferrocenyl-2-hydroxybenzylideneimine Pages 183-186 Mümtaz Erta, Vefa Ahsen, Ayegül Gürek, Özer Bekârolu

Synthesis of the first 30-electron triple-decker complexes of the iron group metals with cyclopentadienyl ligands. X-Ray structure of [(η-C5H5)Ru(μ,η-C5Me5) Ru(η-C5Me5)]PF6 Pages 187-197 A. R. Kudinov, M. I. Rybinskaya, Yu. T. Struchkov, A. I. Yanovskii, P. V. Petrovskii

Cluster chemistry : LIII. Preparation and some substitution reactions of bis(arylimido)triruthenium complexes: X-ray structures of Ru3(μ 3-NPh) (μ3-NC6 H4 F-3) (CO)9 and Ru3(μ3-NPh)2(CO)8(L) (L = CNC6H3Me2-2,6 and PPh3) Pages 199-219 Michael I. Bruce, Mark G. Humphrey, Omar bin Shawkataly, Michael R. Snow, Edward R. T. Tiekink

Bridging alkyls in d-transition metal chemistry: Reactions of (cod) 2M2(μ-R)2 with organolithium reagents to give (cod)2M2(R)4Li2, where M is Rh or Ir, and the crystal structure of (cod)2Rh2(CH2SiMe3)4Li2 and (cod) Rh( CH2SiMe3)2Li(Me2NCH2CH2NMe2) Pages 221-236 Matthew A. Kulzick, Richard A. Andersen, Earl L. Muetterties, Victor W. Day

1,3,2-Oxazaphosphorinanes in rhodium(I) complexes Pages 237-247 E. E. Nifantyev, A. T. Teleshev, T. A. Shikovets, A. R. Bekker, A. N. Chernega, M. Yu. Antipin and, Yu. T. Struchkov

Synthesis and characterization of pentadienyl-iridium(III) and-rhodium(III) complexes Pages 249-255 Chia-Chun Chen, Rai-Shung Liu

Addition of organic halides to bis{(2-vinylphenyl) diphenylphosphine} palladium(0). X-Ray structure of the chelate σ-alikylpalladium(II) complex PdI{o-CH(CH3)C6H4PPh2} - {(E)-o-Ph2PC6H4CH=CHC6H6} Pages 257-269 Martin A. Bennett, Pramesh N. Kapoor

Palladium-catalysed N,N′-disubstituted urea synthesis by oxidative carbonylation of amines under CO and O2 at atmospheric pressure Pages 271-278 Potenzo Giannoccaro

Synthesis and crystal structure of a polymeric complex between 1-penten-3-one and copper(1) chloride Pages 279-285 Mikael Håkansson, Susan Jagner, Martin Nilsson

Issue 3, Pages 287-468 (15 December 1987)

α-Bromo-, α-chloro-, and α-trimethylsilyl-zinc ester enolates. New and universal Reformatsky-type Darzens and Peterson reactions Pages C33-C36 Alois Füstner

Author index Pages C61-C62

Trimethylsilylation of carbenoids generated in situ from allyl and benzyl halides Pages C41-C43 H. Andringa, Y. A. Heus-Kloos, L. Brandsma

Organic anions : IX. Applications of point charge and HSE force field models to group 1 organometallic terameric and hexameric aggregates Pages C25-C32 Richard J. Bushby, Helen L. Steel

Reaction de Reformatsky diastéréospécifique sur un aldéhyde arène chrome tricarbonyle chiral Pages C47-C49 Jacques Brocard, Lydie Pelinski, Jacques Lebibi

Synthesis and lithiation oftricarbonyl(methylbenzo[b]thiophene)chromium complexes Pages C44-C46 Jack L. Davidson, Hasmitta Patel, Peter N. Preston

Komplexe mit Phosphinomethan- und methanidliganden : XIV. [μ-(Me3Si)C(PMe2)2]3Ge4Cl2+ [GeCl3]−, ein di-spirocyclischer Germylen-Kationkomplex mit gewinkelter Ge4-Kette Pages C37-C40 Hans Heinz Karsch, Brigitte Deubelly, Jürgen Riede, Gerhard Müller

Subject index Pages C63-C68

Convenient synthetic routes to MePdII, Me2PdII, and Me3PdIV complexes. The crystal structure of the MePdII complex [MePd(2,2′-bipyridyl)(γ-picoline)]BF4 Pages C55-C60 Peter K. Byers, Allan J. Canty, Brian W. Skelton and, Allan H. White

Ligand exchange between metals: synthesis and characterisation of binuclear and trinuclear iron-alkyne complexes. Crystal structures of [(η5-C5H5)2Fe3(CO)3(μ3-CO)(μ-CO)(CF3C2CF3] and [{μ-CF3CC(CF3)S} {Fe(CO)3}2] Pages C50-C54 René Rumin, François Y. Pétillon, Allan H. Henderson, Ljubica Manojlovi-Muir and, Kenneth W. Muir

Asymmetric grignard cross-coupling reaction between (E)-β-bromostyrene and 1-phenylethylmagnesium chloride Pages 287-292 H. -J. Kreuzfeld, Chr. Döbler, H. -P. Abicht

Orthomanganated arenes in synthesis : III. Transmetallation of orthomanganated aryl ketones by mercuric chloride; synthesis of ortho-acyl-substituted aryl-mercury(II) compounds Pages 293-298 Janine M. Cooney, Louie H. P. Gommans, Lyndsay Main, Brian K. Nicholson

Synthesis of trialkyl-gallium and -indium adducts of tetramethyldiphosphine Pages 299-305 H. D. Hodes, A. D. Berry

Siliciumhaltige Carben-Komplexe : IX. Thermische Fragmentierung von Alkoxy(triphenylsilyl) carben-Komplexen, (CO)5MC(OR)SiPh3 (M = Cr, Mo, W) Pages 307-315 Ulrich Schubert, Hannelore Heörnig

Trimethylsilyl ester radical cations: An ESR study Pages 317-321 Christopher J. Rhodes

Chemie Polyfunktioneller Molekülle , : XCIX. Hydrolyse und oxidative Hydrolyse von Tetrakis[(diiodarsino) methyl]methan. Kristallstrukturanalyse eines Organoarsenoxid-Arsonigsäure-Derivats Pages 323-335 Jochen Ellermann, Ludwig Brehm, Eberhard Köck, Ekkehard Lindner, Wolfgang Hiller and, Riad Fawzi

Einschiebung von Alkenen und Alkinen in die As---H-Bindungen von Cr(CO)5]As(C6H5)H2 Pages 337-342 Lutz-R. Frank, Ibrahim Jibril, Laszlo Zsolnai, Gottfried Huttner

EPR spectra of products of the reaction of di-η5-cyclopentadienyl(diethylalanedi-μ-chloro)titanium(III) with C1 compounds Pages 343-348 S. K. Tyrlik, A. Korda, L. Poppe, A. Rockenbauer and, M. Györ

Reactions of deprotonated sulphur-donor complexes of pentacarbonylchromium(0) with carbon disulphide or carbon diselenide Pages 349-360 Helgard G. Raubenheimer, Simon Lotz, Gert J. Kruger, Antonie van A. Lombard, Joey C. Viljoen

Reaktionen der substituierten metallacyclischen Alkenylketon-Komplexe Cp*(CO)2M[R1C=CR2C(O)Me] (M = Cr, Mo, W; Cp* = η5-C5Me5; R1, R2 = H, Me,Ph) mit Stickstoffmonoxid und Nitrosylchlorid Pages 361-370 Helmut G. Alt, Ulrike Freytag, Max Herberhold, Heidi I. Hayen

Study of redox reactions of bis(arene) chromium complexes by the rotating disk electrode technique IV. Electrochemical oxidation and ionization potentials of bis(arene) chromium complexes Pages 371-376 L. P. Yur'eva, S. M. Peregudova, D. N. Kravtsov, A. Yu. Vasil'kov, L. N. Nekrasov, N. L. Asfandiarov, M. M. Timoshenko, Yu. V. Chizhov

Reactions of [WI2(CO)(NCMe)(η2-RC2R)2] (R = Me or Ph) with carbon monoxide to give either [WI2(CO)2(η2-MeC2Me)2] or [W(-I) I(CO) (η2-PhC2Ph)2]2. Crystal structure of [WI2(CO) 2( η2-MeC2Me)2] Pages 377-383 Elaine M. Armstrong, Paul Ko Baker, Michael G. B. Drew

Synthetic and electrochemical studies on alkynyl complexes of iron and ruthenium Pages 385-392 Caroline Bitcon, Mark W. Whiteley

Bis(trifluormethylisocyanid)-(η-pentamethylcyclopentadienyl)-cobalt. Darstellung und Oxidation zu Trifluormethylisocyanid-(η-pentamethylcyclopentadienyl)-dihalogeno-cobalt Pages 393-396 Dieter Lentz, Brigitte Pötter

Vinylidene transition-metal complexes : I. Novel rhodium(I) and rhodium(III) complexes containing alkynes, alkynyls, and vinylidenes as ligands.Crystal structure of IC5H5Rh(=C=CHPh)(PPri3) Pages 397-411 H. Werner, J. Wolf, F. J. G. Alonso, M. L. Ziegler and, O. Serhadli

Vinyliden-Übergangsmetallkomplexe : II. Die Protonierung der Vinyliden-Komplexe C5H5Rh(=C=CHR)(PPri3) und ihre stufenweise Umwandlung in Vinyl- und α-Halogenalkyl-Rhodiumverbindungen Pages 413-428 J. Wolf, H. Werner

Olefin ligands : II. Syntheses of 2,6-diallylpyridine (DAP) complexes of iridium(I), ruthenium(II), palladium( II) and platinum(II); crystal structures of [RuCl2(PPh3)(DAP)] and [PdCl2(DAP)2] Pages 429-439 Giuseppe Vasapollo, Cosimo Francesco Nobile, Mario Latronico, Maurizio Lanfranchi and, Maria Angela Pellinghelli

Crystal structure of tetrakis(trimethyl-μ-S,S,N-thiocyanatoplatinum), [{Pt(CH3)3SCN}4] Pages 441-445 Blake Vance

First synthesis of an olefin-coordinated platina(II)cyclobutane and its conversion into diphosphineplatina(II)cyclobutanes Pages 447-452 H. J. R. de Boer, O. S. Akkerman, F. Bickelhaupt

Pentafluorophenyl(dithiocarbamate)gold(III) complexes. Crystal and molecular structure of (C6F5)2Au{S2CN(CH2Ph)2} Pages 453-460 Rafael Usón, Antonio Laguna, Mariano Laguna, M. Luz Castilla, Peter G. Jones and, Karen Meyer-Bäse

Synthesis and reactivity of neutral complexes of the types [AuX3(ylide)l and trans-[Au(C6F5)X2(ylide)] (X = halide or pseudohalide). X-ray structure of [Au(SCN)3(CH2PPh3)] Pages 461-468 Rafael Usón, Antonio Laguna, Mariano Laguna, M. Concepcion Gimeno, A. Pablo, Peter G. Jones, Karen Meyer-Bäse and, C. F. Erdbrügger